Synthesis and Catalytic Activity in the Hydrogenation Reaction of Palladium-Doped Metal-Organic Frameworks Based on Oxo-Centered Zirconium Complexes

Metal-nanocluster-doped porous composite materials are attracting considerable research attention, due to their specific catalytic performance. Here we report a simple, cheap, and efficient strategy for the preparation of palladium hydrogenation catalysts based on metal-organic frameworks (MOFs). It has been shown that synthesis Pd/MOF results in formation nanoparticles uniformly fixed surface. The composition structure resulting composites were studied using elemental analysis, DSC, TGA, XRD, TEM, IR spectroscopy. Pd with an average diameter 8–12 nm successfully confined UiO-type MOFs, obtained nanocomposites exhibited abundant porosity, high stability, large surface area. systems activity, selectivity, stability reduce phenylacetylene allyl alcohol styrene propanol, respectively, liquid-phase reactions.